Distribution potential in small liquid-liquid systems

2020-02-13 01:36:02

oil liquid distribution interface potential

责任者: Markin, V.S.;Volkov, A.G. 单位: Dept. of Anesthesiology, UT Southwestern Med. Center, Dallas, TX, USA 来源出处: Journal of Physical Chemistry B(J. Phys. Chem. B (USA)),9 Sept. 2004,108(36):13807-12 摘要: For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/eo, then the solution can be found numerically 关键词: drops;electric potential;interface phenomena;oils;water;distribution potential;liquid-liquid systems;oil-water interface;analytical solution;nanoheterogeneous system;electroneutrality;oil droplet thickness;Debye screening length;H2O