Molecularly assembled nanostructures of a redox-active organogelator

2019-09-11 20:18:56

films 2005 structures Blodgett Hasegawa

责任者: Akutagawa, Tomoyuki;Kakiuchi, Keiko;Hasegawa, Tatsuo;Noro, Sin-Ichiro;Nakamura, Takayoshi;Hasegawa, Hiroyuki;Mashiko, Sinro;Becher, Jan 单位: Research Institute for Electronic Science, Hokkaido University, Sapporo 060-0812, Japan 来源出处: Angewandte Chemie - International Edition,2005,44(44):7283-7287 摘要: (Chemical Equation Presented) Introduction of an ethylenedithio group into an amphiphilic bis(tetrathiafulvalene) annulated macrocycle results in the formation of organogels which produce nanodot-array structures in Langmuir-Blodgett films (see picture). Chemical oxidation of the sulphur-containing π-electron system afforded size-controllable electrically conducting nanodot structures. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA. 关键词: Organic compounds;Nanostructured materials;Molecular dynamics;Assembly;Redox reactions;Sulfur;Gels;Langmuir Blodgett films;Thin films;Electrons;Oxidation;Conducting materials;Molecular electronics;Nanostructures;Nanodot-array structures